Search results for " PAHs"
showing 10 items of 14 documents
Comparison of different methods for extraction of polycyclic aromatic hydrocarbons (PAHs) from Sicilian (Italy) coastal area sediments.
2012
This paper describes a work aimed at improving the conditions of an extraction method, coupling GC-MS determination, for the analysis without cleanup phase, of polycyclic aromatic hydrocarbons (PAHs) from sediment samples. The automatic Soxhlet extraction in warm mode (using Extraction System B-811 Standard, Buchi) has demonstrated advantages for automation, reduced extraction time, and lower solvent use than for conventional Soxhlet extraction. Under these conditions, the recoveries are very good as they resulted greater than 85 % and, in most of the cases, near 100 %. The repeatability is also satisfactory (relative standard deviation less than 15 %). The detection limits are also accepta…
The PAH composition of surface sediments from Stagnone coastal lagoon, Marsala (Italy)
2006
Abstract This paper examines the presence, distribution, nature and sources of 22 Aromatic Hydrocarbons (PAHs), which are important environmentally and toxicologically, in sediments from the Stagnone coastal lagoon at Marsala (Italy). Analysis was performed by gas chromatography/mass spectrometry (GC/MS) with selected ion monitoring (SIM). The total concentration of polycyclic aromatic hydrocarbons ranged from 72 to 18381 μg/kg of dry matrix. The relative standard deviation (RSD) of the replicates on the concentrations of individual compounds ranged from 5% to 20%. The accuracy of method was estimated by analyzing “blank” samples added of known quantities of analytes and the recover percent…
Isomer effects in fragmentation of Polycyclic Aromatic Hydrocarbons
2015
We have observed significant differences in the fragmentation patterns of isomeric Polycyclic Aromatic Hydrocarbon (PAH) cations following collisions with helium atoms at center-of-mass energies around 100 eV. This is in contrast to the situation at other collision energies or in photo-absorption experiments where isomeric effects are very weak and where the lowest-energy dissociation channels (H- and C2H2-loss) domihate in statistical fragmentation processes. In the 100 eV range, non-statistical fragmentation also competes and is uniquely linked to losses of single carbon atoms (CHx-losses). We find that such CHx-losses are correlated with the ionic ground state energy within a given group…
Possible impacts of Hg and PAH contamination on benthic foraminiferal assemblages: An example from the Sicilian coast, central Mediterranean
2007
The Palermo and Augusta urban/industrial areas (Sicily) are examples of contaminated coastal environments with a relatively high influx of unregulated industrial and domestic effluents. Three sediment box-cores were collected offshore of these urban/industrial areas in water depths of 60-150 m during two cruises (summers 2003/2004), dated by (210)Pb and (137)Cs, and analysed for total mercury concentration and total polycyclic aromatic hydrocarbon (PAH) concentration. Benthic foraminiferal assemblages were also examined (in terms of their distribution and morphology) to assess the potential use of benthic foraminifera as bioindicators of pollutant input and environmental change in these Med…
Pelargonium leaves as bioaccumulator of polynuclear aromatic hydrocarbons: Analysis and evaluation of sources and air quality in Palermo area
2006
The leaves of Pelargonium zonale have been chosen because this plant is widespread in both the Mediterranean metropolitan and peripheral areas. The paper describes the analytical method, and the results concerning the determination of PAHs in Pelargonium leaves collected in the Palermo area, and their possible origins. The GC-MS method was applied, since identification of all the different compounds with spectra libraries is possible. Samples were analyzed for 22 PAHs. The reported analytical method is complete within 2 hours, and more convenient than that of other researches. Total PAH concentrations in leaves varied between 24-357 g/kg d.w. The relative abundance of the analyzed PAHs can …
Polycyclic aromatic hydrocarbons (PAHs) in indoor dust matter of Palermo (Italy) area: Extraction, GC–MS analysis,distribution and sources
2008
Abstract Studies on indoor pollution are important since people spend more than 80% of their time indoor environments. In this work the method for PAHs analysis in indoor dust (used as passive sampler) and the results relative to samples collected in the area of Palermo are reported. Dust samples for analysis were collected from 45 indoor environments. Total PAHs concentrations in indoor dusts ranged from 36 to 34 453 μg kg −1 d.w. To correlate indoor and outdoor pollution we analyze, also, the particulate matter and PAHs levels samples collected in four stations. The percentage measured in indoor dusts results more low than that found outside. The values of isomeric ratios for the differe…
Characteristics of current roadside pollution using test-monitoring plots
2014
Abstract The aim of the study was the qualitative recognition of the existing roadside pollutants deposited in topsoils located close to roads with high traffic volume. So far, the studies have helped to determine the content of pollutants that accumulated over a long period of time. Traditionally, it has been difficult to distinguish between roadside pollution and pollution from other industrial sources. In order to avoid such problems and to accurately recognize present threats originating from road traffic, test-monitoring plots were installed in Poland (Gliwice and Opole), Germany (Tubingen, Ulm and Boblingen), Finland (Helsinki), Tajikistan (Dushanbe) and China (Lanzhou). To install th…
Effect of solid waste landfill organic pollutants on groundwater in three areas of Sicily (Italy) characterized by different vulnerability
2017
The aim of this study was to obtain information on the presence and levels of hazardous organic pollutants in groundwater located close to solid waste landfills. Eighty-two environmental contaminants, including 16 polycyclic aromatic hydrocarbons (PAHs), 20 volatile organic compounds (VOCs), 29 polychlorinated biphenyls (PCBs), 7 dioxins (polychlorinated dibenzo-p-dioxins, PCDDs) and 10 furans (polychlorinated dibenzofurans, PCDFs) were monitored in areas characterised by different geological environments surrounding three municipal solid waste landfills (Palermo, Siculiana and Ragusa) in Sicily (Italy) in three sampling campaigns. The total concentrations of the 16 PAHs were always below t…
Composition, distribution, and sources of polycyclic aromatic hydrocarbons in sediments of the gulf of Milazzo (Mediterranean Sea, Italy)
2014
This article describes the characterization of Polycyclic Aromatic Hydrocarbons (PAHs) in sediments of Milazzo Gulf (Italy) located in front of an oil refinery and a power plant. The investigated area is characterized by urban and industrial activities. The sixteen PAHs identified by the USEPA, as requiring priority monitoring, and other non USEPA listed PAHs, namely perylene and some methyl derivatives, were investigated The total PAHs concentrations, expressed as ∑ 19 PAH ranges from 5.6–7402 μg/Kg d.w., with a mean value of 492 μg/Kg d.w. The concentrations of PAHs found in 64 out of 67 samples were lower than the effect range low (ERL = 2460 μg/Kg) concentration, while the remaining sam…
Highly contaminated areas as sources of pollution for adjoining ecosystems: The case of Augusta Bay (Central Mediterranean).
2014
An assessment of trace element and polycyclic aromatic hydrocarbon (PAH) contamination based on surface sediments collected in summer 2012 was carried out in Priolo Bay adjoining one of the most polluted areas of the Mediterranean Sea, the industrial Augusta harbour (Italy, Central Mediterranean). Inorganic and organic contaminants were generally not remarkable. Occasional elevated concentrations of Hg, Cd, Ni and PAHs exceeding sediment quality guidelines were detected in the northern sector of Priolo Bay, close to Augusta harbour, possibly as a result of water drainage of industrialised and urbanised areas and/or potential direct export of contaminated material from Augusta harbour, whose…